Crystalline Fructose Material Safety Data Sheet (MSDS)

Identification

Product Name: Crystalline Fructose
Chemical Formula: C6H12O6
CAS Number: 57-48-7
Synonyms: D-fructose, Fruit Sugar, Levulose
Recommended Use: Food additive, sweetener, ingredient in beverages, pharmaceuticals, and personal care products
Manufacturer: Major ingredient suppliers and food chemical producers across North America, Asia, and Europe
Emergency Telephone Number: Refer to local national emergency response contacts or the company-specific line provided on shipping paperwork

Hazard Identification

GHS Classification: Not considered hazardous by OSHA hazard communication standards
Signal Word: None
Hazard Statements: May cause mild eye or respiratory irritation through dust exposure
Pictograms: None required
Precautionary Statements: Avoid breathing dust, wash skin thoroughly after handling, avoid generating airborne dust, use in well-ventilated areas
Routes of Entry: Inhalation, eye or skin contact, ingestion
Chronic Effects: No chronic health effects documented under typical conditions
Target Organs: None identified for occupational exposure

Composition / Information on Ingredients

Chemical Name: Fructose
Common Name: Crystalline Fructose
Concentration: Typically >99.5%
Impurities: Trace moisture (<0.5%), possible trace sugars such as glucose or sucrose depending on production process
Additives: None intentionally added

First Aid Measures

Eye Contact: Rinse with plenty of water for several minutes, seek attention if irritation persists
Skin Contact: Wash exposed areas with mild soap and water, remove contaminated clothing
Inhalation: Move to fresh air, seek medical attention if respiratory symptoms occur
Ingestion: Rinse mouth with water, drink water to dilute, get medical help if large amounts are swallowed or symptoms develop
Notes for Medical Professionals: Provide symptomatic and supportive care, no known specific antidotes; report large exposures or allergic reactions

Fire-Fighting Measures

Suitable Extinguishing Media: Water spray, dry chemical, foam, or carbon dioxide
Specific Hazards: Burning releases carbon oxides, fine dust airborne may form explosive mixtures
Special Protective Equipment: Firefighters should use self-contained breathing apparatus and protective gear
Advice: Remove containers from fire area if safe, cool unaffected containers with water spray, use care to avoid dust cloud formation under fire conditions

Accidental Release Measures

Personal Precautions: Wear protective goggles, dust mask, gloves
Environmental Precautions: Avoid spill reaching natural waterways
Containment: Use non-sparking tools to sweep up and collect material without generating dust; avoid use of compressed air
Cleaning Up: Place collected material in suitable containers for disposal, ventilate area, wash spill site after containment
Recommended Methods: Clean area with water after solid removal, check for residue on floors to prevent slip hazards

Handling and Storage

Safe Handling: Minimize personal dust exposure, avoid ingestion, use local exhaust ventilation when handling large quantities, keep away from heat or hot surfaces to reduce dust ignition risks
Storage Conditions: Store in tightly closed containers, keep in cool, dry, well-ventilated areas, keep away from strong oxidizers
Incompatible Materials: Avoid strong acids, strong bases, and oxidizing agents
Special Practices: Maintain clean work areas, keep containers sealed except during use, label containers adequately

Exposure Controls and Personal Protection

Exposure Limits: No established exposure limits by OSHA, NIOSH or ACGIH
Engineering Controls: Local exhaust or general ventilation to limit airborne dust
Personal Protection: Respiratory mask (NIOSH-approved) for dust, protective goggles for eyes, gloves for sensitive skin
Hygiene Measures: Wash hands before breaks and after finishing work; avoid eating, drinking, or smoking in handling areas
Environmental Controls: Prevent large quantities from entering watercourse

Physical and Chemical Properties

Appearance: White crystals or powder
Odor: Odorless
Odor Threshold: Not applicable
pH: 5.0-7.0 (10% solution)
Melting Point: 101-103°C
Boiling Point: Decomposes before boiling
Flash Point: Not applicable
Flammability: Not classified as flammable, dust can be combustible
Solubility: Highly soluble in water
Vapor Pressure: Not applicable
Relative Density: 1.6 g/cm³
Partition Coefficient: Not available
Decomposition Temperature: Above 130°C

Stability and Reactivity

Chemical Stability: Stable under normal conditions of storage and use
Reactivity: No significant reactivity with commonly used materials
Hazardous Reactions: Strong oxidizing agents may cause reaction
Conditions to Avoid: High temperatures, sources of ignition, formation of dust clouds
Decomposition Products: Carbon monoxide, carbon dioxide under combustion

Toxicological Information

Acute Toxicity: Oral LD50 (rat) >15,000 mg/kg indicates very low toxicity
Skin Corrosion/Irritation: Not expected to cause irritation
Serious Eye Damage/Irritation: May cause temporary discomfort
Respiratory Sensitization: Dust exposure can irritate upper respiratory tract
Carcinogenicity: No evidence of carcinogenic effects, not listed by IARC, NTP, OSHA
Reproductive or Developmental Effects: No effects reported in available literature
Long-term Exposure: No data suggest chronic effects from routine use

Ecological Information

Ecotoxicity: Not expected to pose a risk in the environment
Persistence and Degradability: Readily biodegradable in water and soil
Bioaccumulation Potential: Does not bioaccumulate; metabolized by organisms
Mobility in Soil: High solubility, likely to leach through soil
Other Adverse Effects: Overloading natural waters with sugar could impact oxygen levels indirectly

Disposal Considerations

Recommended Disposal: Dispose of in accordance with local and national regulations
Unused Product: Can be landfilled as a non-hazardous material or incinerated in a permitted facility
Contaminated Packaging: Empty containers should be rinsed and recycled or disposed of in the same manner as product
Sewage Disposal: Avoid uncontrolled discharge into sewers or waterways

Transport Information

UN Number: Not regulated for transport
Proper Shipping Name: Crystalline Fructose
Hazard Class: Not classified as hazardous
Packing Group: Not applicable
Special Precautions: Keep packaging secure to avoid spillage and dust release
Marine Pollutant: Not regulated as a marine pollutant
Transport in Bulk: Transport according to local, national, and international regulations without special requirements

Regulatory Information

TSCA Status: Listed
FDA Status: Approved for use in food applications
Regulatory Listings: Not regulated as a hazardous substance by key international standards
Label Requirements: General labeling for food or technical chemicals, no hazard symbols
Workplace Safety: Refer to OSHA Hazard Communication Standard for general good practice
Other: Not controlled under SARA Title III, CERCLA, or RCRA hazardous waste regulations